New paper bringing some good old physical-organic chemistry into solid-state mechanochemistry

January 20, 2023.

What if it wasn't necessary to have brand new mechanisms for mechanochemistry? A new collaboration with Francesco Delogu and by our PhD students, Leonarda Vugrin and Maria Carta.

Chem. Commun., 2023,59, 1629-1632

We use two tools: Raman monitoring and mechanochemistry-specific kinetic analysis, to establish a correlation between the reaction probability and the Hammett constants in mechanochemical reactions. These results implicate that the body of knowledge accumulated in physical-organic chemistry could be used in mechanochemistry to predict and plan reactions.

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